Unexpected reactivity of two-coordinate palladium–carbene complexes; synthetic and catalytic implications
- 11 July 2001
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 15,p. 1388-1389
- https://doi.org/10.1039/b104297c
Abstract
Ligand exchange reactions reveal unexpected lability of the carbene ligands in two coordinate palladium(0) N-heterocyclic carbene complexes; the latter are found to be very effective catalysts for amination of aryl chlorides.Keywords
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