N.m.r. evidence for a fluxional allyl-hydride species featuring an aliphatic C–H … IrIIIinteraction
- 1 January 1981
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 11,p. 506-507
- https://doi.org/10.1039/c39810000506
Abstract
The [Ir(H)(PPh3)2(η3-2,3-Dimethylbutenyl)]+ ion has been identified in CD2Cl2 solution from its 1H,2H and 31P n.m.r. spectra, which reveal a novel C–H … IrIII interaction and a fluxional process involving facile hydrogen transfer between metal and hydrocarbon.Keywords
This publication has 0 references indexed in Scilit: