A new, general strategy for achieving planar tetracoordinate geometries for carbon and other second row periodic elements
- 1 January 1991
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 21,p. 1536-1538
- https://doi.org/10.1039/c39910001536
Abstract
Highly stable structures with planar tetracoordinate central atoms, Al4O, Al4N–, Al3SiN, cis-Al2Si2C, trans-Al2Si2C and AlSi3B, are predicted computationally at the ab initio MP4SDTQ/6-311 + G*//MP2(full)/6-31G* level.Keywords
This publication has 24 references indexed in Scilit:
- Structure and bonding in dilithiomethaneJournal of the American Chemical Society, 1984
- Enthalpies of formation of fused cyclobutane derivativesJournal of the American Chemical Society, 1982
- The [4.4.4.4]Fenestranes and[2.2.2.2]paddlane. Prospects for the realization of planar tetracoordinate carbon?Tetrahedron Letters, 1981
- On the planarity of tetracoordinate carbon enclosed by annulene perimetersTetrahedron, 1981
- Planar tetraco-ordinate carbon candidates: MNDO calculations on substituted phenyl-lithium dimersJournal of the Chemical Society, Chemical Communications, 1981
- Molecular orbital study of tetrahedral, planar, and pyramidal structures of the isoelectronic series BH4-, CH4, NH4+, AlH4-, SiH4, and PH4+Journal of the American Chemical Society, 1980
- Stabilization of planar tetracoordinate carbonJournal of the American Chemical Society, 1976
- Applications of qualitative molecular orbital theoryAccounts of Chemical Research, 1974
- The theoretical design of novel stabilized systemsPublished by Walter de Gruyter GmbH ,1971
- Planar tetracoordinate carbonJournal of the American Chemical Society, 1970