Infrared chemiluminescence investigation of the abstraction reactions between fluorine atoms and unsaturated compounds
- 15 April 1975
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 62 (8) , 3061-3065
- https://doi.org/10.1063/1.430904
Abstract
The abstraction reaction between fluorine atoms and various olefinic and aromatic substrates has been examined by the arrested relaxation infrared chemiluminescence technique. The relative populations of each rotational–vibrational quantum state of the HF produced in such reactions have been obtained. The fraction of reaction exothermicity entering HF vibration, as well as the relative total cross sections for the substitution and abstraction reactions have been estimated. The results indicate that, typically, about 40% of the exothermicity enters HF vibration, with the HF V=1 state the most likely to be populated, followed by V=2 and V=3.Keywords
This publication has 20 references indexed in Scilit:
- Estimate of the stabilization energy of the benzyl radical via HF+ infrared chemiluminescence from C6H5CH3 + F .far. HF+ + C6H5CH2Journal of the American Chemical Society, 1974
- Trajectory studies of abstraction reactions. Fluorine atoms with substituted methanes and deuterium atoms with chloroiodideThe Journal of Physical Chemistry, 1973
- Hydrogen fluoride and deuterium fluoride infrared chemiluminescence and energy partitioning from the reactions of fluorine atoms with C6-C10 cycloalkanes and propane-d6The Journal of Physical Chemistry, 1973
- Laboratory angular dependence and the recoil-energy spectrum of the products of the reaction F+C6D6→ D+C6D5FThe Journal of Chemical Physics, 1973
- Infrared chemiluminescence and energy partitioning from the reactions of fluorine atoms with the primary carbon-hydrogen bonds of alkanes, halogenated methanes, and tetramethyl silaneThe Journal of Chemical Physics, 1973
- Computation of electric dipole matrix elements for hydrogen fluorideJournal of Quantitative Spectroscopy and Radiative Transfer, 1973
- Energy Distribution Among Reaction Products. VI. F+H2, D2The Journal of Chemical Physics, 1972
- Quenching of Infrared Chemiluminescence: Rates of Energy Transfer from HF (v ≤ 5) to CO2 and HF, and from DF (v ≤ 3) to CO2 and HFThe Journal of Chemical Physics, 1972
- Concepts in reaction dynamicsAccounts of Chemical Research, 1972
- Infra-red chemiluminescence I. Infra-red emission from hydrogen chloride formed in the systems atomic hydrogen plus chlorine, atomic hydrogen plus hydrogen chloride, atomic hydrogen plus deuterium chloride, and atomic deuterium plus hydrogen chlorideProceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences, 1960