Syntheses de Phenylhydro-Digermanes et-Trigermanes et des Phenylhalogenopolygermanes Correspondants
- 1 January 1972
- journal article
- research article
- Published by Taylor & Francis in Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry
- Vol. 2 (1) , 57-63
- https://doi.org/10.1080/00945717208069579
Abstract
Sym-diphenyl-and tetraphenyl- hydrodigermanes were obtained in about 75% yield by phenylchlorogermane or diphenylchlorogermane coupling with magnesium amalgam. A similar reaction with phenylchloro-and phenyldichloro-germane leads to 1,2,3-triphenyltrigermane. Radical halogenation of phenylhydropolygermanes with carbon tetrahalides and N-halosuccinimides give the corresponding phanylhalodi-and trigermane.Keywords
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