Crystal structure of bis(benzo[h]quinolin-10-yl-C 10,N)dicarbonylruthenium(II)
- 1 January 1983
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 9,p. 2121-2123
- https://doi.org/10.1039/dt9830002121
Abstract
The crystal structure of the cis isomer of the title compound, cis-[Ru(CO)2(bquin)2](bquin = benzo[h]quinolin-10-yl), has been established at 295 K by single-crystal X-ray diffraction methods, and refined by least squares to a residual of 0.037 for 1 242 independent ‘observed’ reflections. Crystals are monoclinic, space group Pn, with a= 13.682(4), b= 10.885(3), c= 7.497(2)Å, β= 104.05(2)°, and Z= 2. the two carbonyl groups [Ru–C 1.87(1) and 1.81(1)Å] lie trans to the two ligand nitrogen atoms [Ru–N 2.15(1) and 2.16(1)Å]; Ru–C(ligand) are 2.13(1) and 2.12(1)Å.Keywords
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