Novel binuclear copper(I) complexes with unusual azide and thiocyanate bridges. Crystal structures of [Cu2(μ-Ph2Ppypz)2(μ-1,1-N3)][ClO4]·Et2O and [Cu2(μ-Ph2Ppypz)2(μ-1,1-SCN)][ClO4] [Ph2Ppypz = 2-(diphenylphosphino)-6-(pyrazol-1-yl)pyridine]
- 1 January 1997
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 23,p. 4477-4478
- https://doi.org/10.1039/a706986c
Abstract
The first binuclear copper(I) complex with a µ-1,1-N3 bridge, [Cu2(µ-Ph2Ppypz)2(µ-1,1-N3)][ClO4]·Et2O and [Cu2(µ-Ph2Ppypz)2(µ-1,1-SCN)] [ClO4] [Ph2Ppypz = 2-(diphenylphosphino)-6-(pyrazol-1-yl)pyridine], which exhibits an unusual thiocyanate (µ-1,1-SCN) bridge, have been synthesised and characterised.Keywords
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