Oxygen anion radicals on zeolites

Abstract
Under suitable conditions, the activation of cerium exchanged X and Y zeolites in oxygen or nitrous oxide gives rise to the formation of anion radicals O 2 and O or dianions O2– 2 and O2–, and presumably also O 3 on the zeolites. The superoxide anion radical O 2 has been observed on lanthanum exchanged X and Y zeolites and adsorbed diamagnetic oxygen species on calcium and iron exchanged Y zeolites. The behaviour of the individual adsorbed oxygen species was studied on these zeolites.

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