Non-Markovian stochastic Schrödinger equation
- 24 September 1999
- journal article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 111 (13) , 5676-5690
- https://doi.org/10.1063/1.479868
Abstract
We report a study of a stochastic Schrödinger equation corresponding to the Redfield master equation with slipped initial conditions, which describes the dynamics of a slow subsystem weakly coupled to a fast thermal bath. Using the projection-operator method of Feshbach, we derive a non-Markovian stochastic Schrödinger equation of the generalized Langevin type, which simulates the time evolution of the quantum wave functions of the subsystem driven by the fluctuating bath. For δ-correlated baths, the non-Markovian stochastic Schrödinger equation reduces to the previously derived Markovian one. Numerical methods are proposed to simulate the time evolution under our non-Markovian stochastic Schrödinger equation. These methods are illustrated with the spin-boson model.Keywords
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