A New Class of Materials with Promising Thermoelectric Properties: MNiSn (M = Ti, Zr, Hf)
- 1 January 1997
- journal article
- Published by Springer Nature in MRS Proceedings
Abstract
TiNiSn, ZrNiSn and HfNiSn are members of a large group of intermetallic compounds which crystallize in the cubic MgAgAs-type structure. Polycrystalline samples of these compounds have been prepared and investigated for their thermoelectric properties. With thermopowers of about –200 μV/K and resistivities of a few mΩcm, power factors S2/ρ as high as 38 μW/K2cm were obtained at 700 K. These remarkably high power factors are, however, accompanied by a thermal conductivity which is too high for applications. In order to reduce the parasitic lattice thermal conductivity, solid solutions Zrl−xHfxNiSn, Zrl−xTixNiSn, and Hfl−xTixNiSn were formed. The figure of merit of Zr0.5Hf0.5NiSn at 700 K (ZT= 0.41) exceeds the end members ZrNiSn (ZT= 0.26) and HfNiSn (ZT= 0.22).Keywords
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