Electronic effects in the reactions of olefins with permanganate ion and with osmium tetroxide
- 1 January 1966
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society B: Physical Organic
- p. 803-807
- https://doi.org/10.1039/j29660000803
Abstract
The oxidation of olefins (alicyclic compounds and stilbenes) by permanganate ion is accelerated by electron-attracting substituents, but these groups retard the reactions of the olefins with osmium tetroxide. For the stibene oxidations, approximate ρ values obtained were: 0·65 for the permanganate reactions in aqueous dioxan and –0·55 for the osmium tetroxide reactions in dioxan.Keywords
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