The nature and decomposition pathways of SiH−5, PH5, and SH+5, the simplest viable pentavalent molecules
- 6 February 1987
- journal article
- Published by Elsevier in Chemical Physics Letters
- Vol. 133 (6) , 553-561
- https://doi.org/10.1016/0009-2614(87)80077-5
Abstract
No abstract availableKeywords
This publication has 18 references indexed in Scilit:
- On the role of d orbitals in sulfur hexafluorideJournal of the American Chemical Society, 1986
- Reaktivität von anionischen, fünffach koordinierten Si‐Komplexen gegenüber NucleophilenAngewandte Chemie, 1986
- Theoretical determination of molecular structure and conformation. 17. On the existence of FH2-, OH3-, NH4-, and CH5- in the gas phaseThe Journal of Physical Chemistry, 1986
- Elimination of dihydrogen from collision-activated alkoxide negative ions in the gas phase. An ab initio and isotope effect studyJournal of the Chemical Society, Chemical Communications, 1984
- Why life existsOrganometallics, 1982
- Electronic structure of phosphine. Effect of basic set and correlation on the inversion barrierThe Journal of Physical Chemistry, 1982
- Quantum‐chemical investigation of the silicon and carbon coordination bond in their isostructural compoundsInternational Journal of Quantum Chemistry, 1980
- Large atomic orbital basis SCF and MRD-CI calculations for rearrangements of the PH5 moleculeJournal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics, 1979
- Electronic structure of silane hydride anion (SiH5-) and model studies of inter- and intramolecular exchange in pentacoordinate silicon species. Ab initio investigationJournal of the American Chemical Society, 1973
- Molecular orbital theory of pentacoordinate phosphorusJournal of the American Chemical Society, 1972