ESR Studies of Unsubstituted Cyclic Nitroxides in Solids
- 15 January 1972
- journal article
- conference paper
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 56 (2) , 707-709
- https://doi.org/10.1063/1.1677219
Abstract
A new photochemical method of producing nitroxides from nitramines is reported. Solutions of un‐substituted cyclic nitroxides from nine nitramines were studied in the ESR and splitting constants established. For two cases, single‐crystal studies of nitroxides produced in situ by this reaction permitted neighboring hydrogen interactions with the nitroxide electron to be compared with the nitrogen interaction.Keywords
This publication has 2 references indexed in Scilit:
- Synthesis and structure of the N‐nitropyrrolidinonesJournal of Heterocyclic Chemistry, 1965
- The Steric Conformations of Nitro- and Nitroso-bis-piperazinesJournal of the American Chemical Society, 1958