α-Keto phosphonoacetates
- 1 January 1989
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 4,p. 246-247
- https://doi.org/10.1039/c39890000246
Abstract
Oxophosphonoacetate (1), a novel biophosphate analogue containing a highly reactve α-ketone function at pH 2), but can be made by oxygen transfer to the α-carbene of ethyl P,P-bis(trimethylsilyl) phosphonoacetate followed by heating in H2O.Keywords
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