Tetramethylenedithiocarbamates of the early transition metals
- 1 January 1972
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 15,p. 1614-1616
- https://doi.org/10.1039/dt9720001614
Abstract
Tetrakistetramethylenedithiocarbamatometals M[S2CN(CH2)4]4(M = NbIV, MoIV, and WIV) have been prepared by reactions of ammonium tetramethylenedithiocarbamate and the respective metal tetrachloride in acetonitrile. The pentakis-compound Ta[S2CN(CH2)4]5 was also prepared. Spectroscopic (u.v., visible, and i.r.) and magnetic susceptibility studies were carried out on the compounds. The niobium, molybdenum, and tungsten compounds appear to be eight-co-ordinate.Keywords
This publication has 0 references indexed in Scilit: