Binaphthyl-Substituted Chiral Phosphines and Oxides from Binaphthophooles and Nucleophiles
- 1 May 1994
- journal article
- research article
- Published by Taylor & Francis in Synthetic Communications
- Vol. 24 (9) , 1271-1278
- https://doi.org/10.1080/00397919408011728
Abstract
Binaphthophospholes 1 are the starting compounds for the synthesis of chiral phosphine oxides 3 or phosphines 4 via reaction of phospholium salts 2 with nucleophiles. The binaphthyl residue acts as a stereochemical probe for monitoring the integrity of the phosphorus stereocenter.Keywords
This publication has 7 references indexed in Scilit:
- Atropisomerism in (±)-7-methyl- and -phenyl-substituted dinaphtho[2,1-b;1′,2′-d]phospholes and dinaphth[2,1-b;1′,2′-d]arsolesJournal of Organometallic Chemistry, 1993
- Centenary Lecture. Chemical multiplication of chirality: science and applicationsChemical Society Reviews, 1989
- The organic chemistry of phospholesChemical Reviews, 1988
- Chiral Ligands for Asymmetric CatalysisPublished by Elsevier ,1985
- Synthesis of phosphines having chiral organic groups ligated to chiral phosphorusThe Journal of Organic Chemistry, 1980
- Stereomutation of phosphine oxides by lithium aluminum hydrideJournal of the American Chemical Society, 1969
- Synthesis and cleavage reactions of some dibenzophosphole derivativesThe Journal of Organic Chemistry, 1969