Ionization and Dissociation of Perchlorylfluoride by Electron Impact
- 1 July 1957
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 27 (1) , 176-179
- https://doi.org/10.1063/1.1743661
Abstract
Relative abundances and appearance potentials are reported for both positive and negative ions observed in the mass spectrum of perchlorylfluoride. Appearance potentials of the atom ions result in a value for ΔHf(ClO3F) of nearly zero within the experimental uncertainty. Bond dissociation energies and ionization potentials of the chloryl radicals are estimated from appearance potentials of the polyatomic ions. The energetics of probable ionization‐dissociation processes are compared with observed data.Keywords
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