Copper-Catalyzed SN2′-Selective Cross Coupling Reaction Between Grignard Reagents and Allylic Phosphates
- 1 January 1993
- journal article
- letter
- Published by Georg Thieme Verlag KG in Synlett
- Vol. 1993 (09) , 689-690
- https://doi.org/10.1055/s-1993-22573
Abstract
The SN2′-selective Grignard coupling with primary allylic diphenylphosphates was successfully achieved in the presence of a catalytic amount of CuCN·2LiCl. γ-Substituted allyl Grignard reagents reacted with allylic phosphates selectively at the less substituted allylic terminus.Keywords
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