The Raman spectra of tricoordinate CdX2Y− halogenocadmate(II) anions in the solid state
- 1 December 1976
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 54 (23) , 3641-3645
- https://doi.org/10.1139/v76-523
Abstract
Anionic complexes of cadmium, of the type [CdX2Y]−, where X and Y are chlorine, bromine or iodine, have been prepared as the tetra-n-propylammonium salts. Raman spectra have been recorded, and serve to establish that these anions have C2v symmetry in the solid state. Force constants calculated on the Urey–Bradley approximation are correlated with previously reported results for CdX3− species.Keywords
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