A Simple, One-Pot Transformation oft-Alkyl Chlorides Into (t-Alkyl)amines

Abstract
t-Alkyl chlorides are readily azidated using trimethylsilyl azide in the presence of tin tetrachloride. Tertiary azides can be transformed without isolation into the corresponding (t-alkyl)amine hydrochlorides in a one-pot procedure employing the Staudinger reaction.

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