Notizen: Kristallstruktur einer Phosphor-Stickstoff-Verbindung mit zweifach koordiniertem, kationisch stabilisierten Phosphor / Crystal Structure of a Phosphorus-Nitrogen Compound with Two-Coordinate Cationic Phosphorus
Open Access
- 1 November 1977
- journal article
- Published by Walter de Gruyter GmbH in Zeitschrift für Naturforschung B
- Vol. 32 (11) , 1342-1343
- https://doi.org/10.1515/znb-1977-1124
Abstract
The crystal structure of a phosphorusnitrogen compound with two-coordinate cationic phosphorus was determined from single crystal X-ray data. The structure of the molecule shows two very short P–N distances (161.4 pm) indicating 3pπ(P)— 2pπ(N) interaction between the phosphorus and the lone pairs of the nitrogen atoms. The N–P–N angle was found to be 97.4°.Keywords
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