Röntgenstrukturanalyse und Schwingungsspektren von Trischwefeldistickstoffdioxid, S3N2O2 [1] / X-ray Structural Analysis and Vibrational Spectra of Trisulfurdinitrogendioxide, S3N2O2 [1]
Open Access
- 1 July 1980
- journal article
- Published by Walter de Gruyter GmbH in Zeitschrift für Naturforschung B
- Vol. 35 (7) , 792-796
- https://doi.org/10.1515/znb-1980-0702
Abstract
A redetermination of the crystal and molecular structure of the chain-like molecule S(NSO)2 resulted in the following molecular parameters: d(SO) = 146.5(2), d(S = N) = 153.4(2), d(S-N) = 165.7(2) pm, bond angles OSN = 117.5(1)°, SNS = 123.6(2)°, and NSN = 97.2(1)°, torsion angles OSNS = -0.3(2)°, and SNSN = -177.7(2)° (molecular symmetry C2). Infrared and Raman spectra of S(NSO)2 are reported and assigned; there is no evidence for conformational changes on dissolution of crystalline S(NSO)2Keywords
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