Zur Strukturchemie der Diperoxovanadate(V): Das μ-Hydroxo-bis [oxo-diperoxovanadat(V)] Anion / Studies on Diperoxovanadates: The μ-Hydroxo-bis [oxo-diperoxovanadate(V)] Anion
Open Access
- 1 February 1979
- journal article
- Published by Walter de Gruyter GmbH in Zeitschrift für Naturforschung B
- Vol. 34 (2) , 242-244
- https://doi.org/10.1515/znb-1979-0220
Abstract
Depending on the pH and the respective concentrations of solutions containing NH4+/NH3/H2O2/NH4VO3 three yellow ammonium salts can be isolated: (NH4)4[O(VO(O2)2)2], NH4[VO(O2)2NH3]; and the novel (NH4)3[HV2O11] · 2 H2O. A cesium and potassium salt of the latter anion have been prepared. The infrared spectra of these salts are interpreted assuming a μ-hydroxo-bis[oxo-diperoxovanadate(V)] structure in the solid state.Keywords
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