Isothiocyanate, VII. Spaltungsreaktionen an α‐Carbäthoxy‐ und α‐Acetyl‐acetthioessigsäureamiden
- 23 August 1966
- journal article
- research article
- Published by Wiley in European Journal of Organic Chemistry
- Vol. 695 (1) , 49-54
- https://doi.org/10.1002/jlac.19666950107
Abstract
N‐Aryl‐substituierte α‐Carbäthoxy‐ und α‐Acetyl‐acetthioessigsäureamide (2 bzw. 6) ergeben nach Abspaltung einer Acetylgruppe Malonsäureäthylester‐thioamide (3) bzw. Acetthioessigsäureamide. Letztere reagieren mit Arylisothiocyanaten unter erneuter Acyl‐Abspaltung zu N.N′‐Diaryl‐dithiomalonsäurediamiden (7).Keywords
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