Activation of carbon diselenide by transition-metal complexes selenocarbonyl derivatives of chromium and manganese
- 1 January 1975
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 3,p. 103-104
- https://doi.org/10.1039/c39750000103
Abstract
Carbon diselenide react in the presence of PPh3 with (π-C5H5)Mn(CO)2(THF) or (π-C6H5CO2Me)-Cr(CO)2(THF) to give (π-C5H5)Mn(CO)2(CSe) and (π-C6H5CO2Me)Cr(CO)2(CSe), the first examples of transitionmetal selenocarbonyls.Keywords
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