ESCA Studies on Some Bromine Compounds Using an Internal Standard for Calibration
- 3 January 1981
- journal article
- research article
- Published by Taylor & Francis in Spectroscopy Letters
- Vol. 14 (2) , 89-94
- https://doi.org/10.1080/00387018108062565
Abstract
The binding energies (Eb) of the Br (3P3/2) level have been recorded for some bromine compounds to characterize the relation between Eb and the atomic charge qBr. As an internal standard the Cls binding energy of the carbons of incorporated phenyl groups have been used. From this relation the charges on the metal atoms in FeBr− 4, CoBr2- 4, NiBr2- 4 have been estimated as +1.0, +0.7 and +0.9, respectively.Keywords
This publication has 2 references indexed in Scilit:
- The Use of Internal Standards for Measuring the ESCA Chemical Shift in Coordination Compounds of CobaltPhysica Scripta, 1977
- An interpretation of 1H and 13C chemical shifts in substituted benzenes on the basis of M.O. charge densitiesMagnetic Resonance in Chemistry, 1971