Synthesis of Z-α,β-Ethylenic N-Boc-γ-Amino Esters from Nitrones

Abstract
The reduction of γ-N-hydroxylamino-α,β-acetylenic esters bearing a methoxy-substituted benzyl group on the nitrogen atom by zinc in a MeOH/AcOH mixture leads stereoselectively to Z-γ-amino-α,β-ethylenic esters.

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