Vibronic model leading to orthorhombic Jahn-Teller distortions
- 15 December 1982
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review B
- Vol. 26 (12) , 6438-6443
- https://doi.org/10.1103/physrevb.26.6438
Abstract
The eigenvalue problem for the dynamic Jahn-Teller system of an orbital triplet in cubic symmetry coupled to and vibrational modes has been solved numerically with the simultaneous inclusion of both the linear and quadratic coupling terms. The possibility of orthorhombic Jahn-Teller distortion has been found from the appearance of a nearly-sixfold-degenerate () ground state in the case when an -type quadratic coupling term or a bilinear coupling term has been considered. The computed result of Ham's reduction factors in the ground state shows the orthorhombic property.
Keywords
This publication has 8 references indexed in Scilit:
- GaAs:—an orthorhombic Jahn-Teller center with a stress-dependent reorientation ratePhysical Review B, 1980
- Jahn-Teller effects in paramagnetic crystalsPhysics Reports, 1978
- Dynamic Jahn-Teller vibronic coupling for an orbital triplet:andPhysical Review B, 1978
- Coexistence of tetragonal with orthorhombic or trigonal Jahn-Teller distortions in ancomplex: A plausible interpretation of alkali-halide phosphors luminescencePhysical Review B, 1975
- A possibility of orthorhombic Jahn-Teller distortionJournal of Physics and Chemistry of Solids, 1970
- Dynamic Jahn-Teller Effect in an Orbital Triplet State Coupled to BothandVibrationsPhysical Review B, 1969
- Studies of the Jahn-Teller effect. I. A survey of the static problemProceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences, 1957
- The Jahn-Teller Effect and Crystalline Stark Splitting for Clusters of the Form XY6The Journal of Chemical Physics, 1939