Metallo-selective substitution reactions by amines or phosphines in HRuCo₃(CO)₁₂.¹H and⁵⁹Co N.m.r. studies of HRuCo₃(CO)_12–xL_x(L = amines or phosphines, x= 0 to 2)

1 January 1986

journal article
research article
Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications

No. 18,p. 1451-1452
https://doi.org/10.1039/c39860001451

Abstract

The substitution of amines for the CO ligand of HRuCo₃(CO)₁₂ takes place preferentially at the ruthenium atom whereas the substitution of phosphines occurs exclusively at the cobalt atoms.

Keywords

PHOSPHINES
SUBSTITUTION
AMINES
XLX
12.1H
RUTHENIUM
PREFERENTIALLY
N.M.R
TAKES
COBALT

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Metallo-selective substitution reactions by amines or phosphines in HRuCo3(CO)12.1H and59Co N.m.r. studies of HRuCo3(CO)12–xLx(L = amines or phosphines, x= 0 to 2)

Abstract

Keywords

Metallo-selective substitution reactions by amines or phosphines in HRuCo₃(CO)₁₂.¹H and⁵⁹Co N.m.r. studies of HRuCo₃(CO)_12–xL_x(L = amines or phosphines, x= 0 to 2)