Solvent-free ruthenium-catalysed vinylcarbamate synthesis from phenylacetylene and diethylamine in ‘supercritical’ carbon dioxide

Abstract
The solvent-free synthesis of β-[(diethylcarbamoyl)oxy]styrene from phenylacetylene and diethylamine in supercritical carbon dioxide is greatly accelerated for a series of ruthenium catalysts compared to the same reactions in toluene.

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