Electrophilic cyclization of polyene allylsilanes. Synthesis of albicanyl acetate
- 1 March 1982
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 60 (5) , 673-675
- https://doi.org/10.1139/v82-098
Abstract
The allylsilanes 5 [Formula: see text] were prepared by a nickel(II) catalyzed coupling of trimethylsilylmethylmagnesium chloride with the enol phosphate of the corresponding β-keto esters. Stannic chloride and mercuric trifluoroacetate effected a cyclization of 5. The product from 5b was converted into the marine natural product, albicanyl acetate (1)[Formula: see text]Keywords
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