Direct Reversible Protein Electrochemistry at a Pyrolytic Graphite Electrode. Characterization of the Redox Thermodynamics of the Fe4S4-Siroheme Prosthetic Center in the Hexameric Dissimilatory Sulfite Reductase and the Monomeric Assimilatory Sulfite Reductase from Desulfovibrio vulgaris (Hildenborough). Systematic pH Titration Experiments and Implications for Active Site Chemistry