Free-Radical Carbonylation by TTMSS Mediated Process
- 1 January 1993
- journal article
- letter
- Published by Georg Thieme Verlag KG in Synlett
- Vol. 1993 (02) , 143-145
- https://doi.org/10.1055/s-1993-22381
Abstract
The use of TTMSS (tris(trimethylsilyl)silane) as a free-radical mediator permits the carbonylation of an aliphatic halide to an aldehyde under reasonably law pressures of carbon monoxide. Furthermore, a three-component coupling process providing unsymmetrical ketones has been achieved using a nearly stoichiometric amount of olefins.Keywords
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