Viscosities of dilute polymer solutions in nematic liquids
- 1 August 1979
- journal article
- research article
- Published by Wiley in Journal of Polymer Science: Polymer Physics Edition
- Vol. 17 (8) , 1367-1374
- https://doi.org/10.1002/pol.1979.180170808
Abstract
A nematic fluid is characterized by five friction coefficients. When dilute polymer coils are added to the fluid, all these coefficients are modified. Three Miesowicz viscosities (measured under an aligning magnetic field) and two coupling coefficients between orientation and flow are discussed. In our calculation, elastic dumbbells are used to model the flexible polymer chains. The results are written in terms of two size parameters R∥ and R⊥ and two chain friction coefficients λ∥ and λ⊥ (the label ∥ refers to a direction parallel to the nematic axis). This could be compared to other experiments (such as translational diffusion) which measure λ∥ and ⊥ directly. They may give useful estimates of coil conformation in nematic solvents.Keywords
This publication has 5 references indexed in Scilit:
- Solubilization of a Polymer Chain in a Nematic Phase; Effect on the Twist ViscosityMolecular Crystals and Liquid Crystals, 1978
- Synthesis and Properties of Aromatic and Extended Chain PolyamidesMacromolecules, 1977
- Polymerization of a nematic monomer: N‐(p‐cyanobenzylidene)‐p‐aminostyreneJournal of Polymer Science Part C: Polymer Letters, 1977
- Liquid Crystal Polymers. II. Preparation and Properties of Polyesters Exhibiting Liquid Crystalline MeltsPublished by Springer Nature ,1977
- Dynamics of Stretched Polymer ChainsMacromolecules, 1977