Prediction of Birefringence for Optical Memory Disk

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Abstract
Polycarbonate (PC) is considered to be a proper resin for optical memory disk, however PC resin shows high birefringence. It is very important to reduce birefringence of PC optical memory disk. This research is to obtain the relationship between birefringence and process conditions and to get the optimum condition for the production of low birefringence substrate of PC optical memory disk. The birefringence distribution of PC optical memory disk was theoretically predicted by the calculations of both the stress distribution caused by molecular orientation during the filling stage and the thermal stress caused by temperature difference during the cooling stage. The relationship between birefringence distribution and the process conditions such as rheological properties of PC resin, injection temperature, mold temperature, mold design and annealing condition is possible to be predicted theoretically by calculating shear stress during the injection process and thermal stress during the cooling process. The predicted results of birefringence distribution qualitatively agree with the experimental ones.

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