Proton transfers to and from sulphur. Part I. Toluene-α-thiol in dimethyl sulphoxide
- 1 January 1974
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 2
- No. 9,p. 1025-1029
- https://doi.org/10.1039/p29740001025
Abstract
Proton transfer from and to the sulphur atom of toluene-α-thiol in anhydrous dimethyl sulphoxide has been followed by n.m.r. spectrosocopy under conditions of both acid (trifluoromethanesulphonic) and base (imidazole) catalysed exchange. The different mechanisms are discussed.Keywords
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