Regioselective Conversion of 1,3-Dienes into β,γ-Unsaturated Esters via Carboalkoxylation of η3-Allyltitanocene Complexes

Abstract
η3-Allyltitanium(III) complexes formed in situ from 1,3-dienes undergo regiospecific addition with methyl chloroformate. The overall transformation constitutes a general one-pot procedure for the conversion of 1,3-dienes into β,γ-unsaturated esters.

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