Azapropellanes as phase-transfer catalysts. I. Introduction and synthesis of (±)1-azoniatricyclo[4.4.4.0^1,6]tetradecane and(±)1-azoniatricyclo[4.4.3.0^1,6]tridecane salts

1 December 1980

journal article
research article
Published by Canadian Science Publishing in Canadian Journal of Chemistry

Vol. 58 (23) , 2604-2609
https://doi.org/10.1139/v80-416

Abstract

The rationale for considering 1-azoniapropellane salts as potential chiral phase-transfer catalysts is presented. The synthesis of 2 examples of these types of molecules is outlined and their efficacy in phase-transfer catalyzed reactions is established. [Chiral phase-transfer catalysts are essential for biomimetric or biogenetic synthesis to be achieved with chiral or achiral reactants.].

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Azapropellanes as phase-transfer catalysts. I. Introduction and synthesis of (±)1-azoniatricyclo[4.4.4.01,6]tetradecane and(±)1-azoniatricyclo[4.4.3.01,6]tridecane salts

Abstract

Azapropellanes as phase-transfer catalysts. I. Introduction and synthesis of (±)1-azoniatricyclo[4.4.4.0^1,6]tetradecane and(±)1-azoniatricyclo[4.4.3.0^1,6]tridecane salts