A New Reaction of 1,2‐Dioxetanes. Formation of 1,2,4‐Trioxanes from Aldehydes
- 14 December 1983
- journal article
- research article
- Published by Wiley in Helvetica Chimica Acta
- Vol. 66 (8) , 2615-2620
- https://doi.org/10.1002/hlca.19830660828
Abstract
1,2‐Dioxetanes bearing different 3‐phenoxy substituents add to aldehydes to give 1,2,4‐trioxanes in yields of 17–75% depending on the nature of the para‐phenyl substituent. Illustrations of this new reaction are described.Keywords
This publication has 13 references indexed in Scilit:
- Reaction of singlet oxygen with enol ethers in the presence of acetaldehyde. Formation of 1,2,4-trioxanesJournal of the American Chemical Society, 1983
- Reaction of bicyclic endo peroxides with carbonyl compounds. A new approach to 1,2,4-trioxanesJournal of the American Chemical Society, 1983
- Total synthesis of qinghaosuJournal of the American Chemical Society, 1983
- The synthesis of spiro[adamantane‐[1,2]dioxetanes]European Journal of Inorganic Chemistry, 1982
- Singlet oxygenation of ketene acetals: formation of 1,2-dioxetanes and their thermal rearrangement to .alpha.-peroxy estersJournal of the American Chemical Society, 1980
- Synthesis of phenyl enol ethers via decarboxylation of .beta.-lactones derived from the lithium .alpha.-phenoxy-.alpha.-lithioacetate synthonThe Journal of Organic Chemistry, 1978
- Reaction of singlet oxygen with norbornenyl ethers. Characterization of dioxetanes and evidence for zwitterionic peroxide precursorsJournal of the American Chemical Society, 1978
- Catalyzed decomposition of tetramethyl-1,2-dioxetane by rhodium and iridium complexesJournal of the American Chemical Society, 1977
- Preparation and Thermolysis of Some 1,2-DioxetanesCanadian Journal of Chemistry, 1975
- Photosensitized Oxygenation of α-Pyran Derived from β-IononeAgricultural and Biological Chemistry, 1973