Alkene Oxidation by a Platinum Oxo Complex and Isolation of a Platinaoxetane
- 8 August 2003
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 125 (35) , 10522-10523
- https://doi.org/10.1021/ja036496c
Abstract
Oxo complex [(1,5-COD)4Pt4(μ3-O)2Cl2](BF4)2 (1) reacts readily with ethylene and norbornylene. The ethylene reaction yields acetaldehyde and a 1:1 mixture of (1,5-COD)Pt(Cl)(CH2CH3) (2) and [(1,5-COD)Pt4(η3-CH2CHCH(CH3))](BF4) (3), while the norbornylene reaction yields a platinaoxetane complex, the first metallaoxetane to be obtained from the reaction of an oxo complex and an alkene.Keywords
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