The autoxidation of a chromium (II) porphyrin: synthesis and structural characterisation by X-ray crystallography of αβγδ-tetraphenyl-porphinato-oxochromium(IV)
- 1 January 1981
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 8,p. 370-371
- https://doi.org/10.1039/c39810000370
Abstract
The reaction of dioxygen with αβγδ-tetraphenyl-porphinatochromium (II) in toluene proceeds in two stages; a µ-oxo-chromium(III) intermediate is formed initially and this then further reacts with dioxygen to give the title complex, the structure of which has been determined by X-ray crystallography.Keywords
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