Synthesis, NMR and Conformational Studies of Fucoidan Fragments 1:1Desulfated 2,3- and 3,4-Branched Trisaccharide Fragments and Constituting Disaccharides
- 1 January 2000
- journal article
- research article
- Published by Taylor & Francis in Journal of Carbohydrate Chemistry
- Vol. 19 (9) , 1151-1173
- https://doi.org/10.1080/07328300008544140
Abstract
Two fucotriosides with vicinal disubstitution α-L-Fuc-(1→2)[α-L-Fuc-(1→3)]α-L-Fuc-OPr (1) and α-L-Fuc-(1→3)[α-L-Fuc-(1→4)]α-L-Fuc-OPr (2), which are related to fragments of natural polysaccharides fucoidans, have been synthesized together with constituent disaccharides 3-5. Spectral and conformational properties of tri- and disaccharides have been investigated by 1H, 13C and NOE NMR spectroscopy.Keywords
This publication has 49 references indexed in Scilit:
- Sulfated Polysaccharides from the Egg Jelly Layer Are Species-specific Inducers of Acrosomal Reaction in Sperms of Sea UrchinsJournal of Biological Chemistry, 1997
- The effect of the selectin binding polysaccharide fucoidin on eosinophil recruitment in vivoBritish Journal of Pharmacology, 1997
- Synthesis and structural studies of branched 2-linked trisaccharides related to blood group determinantsCarbohydrate Research, 1996
- 1H and 13C NMR data for 2‐O‐, 3‐O‐and 2,3‐di‐O‐glycosylated methyl α‐and β‐D‐galactopyranosidesMagnetic Resonance in Chemistry, 1993
- Specificity of binding of zona pellucida glycoproteins to sperm proacrosin and related proteinsJournal of Experimental Zoology, 1993
- A New Procedure for the Isolation of Anti-HIV Compounds (Polysaccharides and Polyphenols) from the Marine Alga Fucus vesiculosusJournal of Natural Products, 1993
- The three members of the selectin receptor family recognize a common carbohydrate epitope, the sialyl Lewis(x) oligosaccharideThe Journal of cell biology, 1992
- Investigations into the Mechanism by Which Sulfated Polysaccharides Inhibit HIV Infection In VitroAIDS Research and Human Retroviruses, 1992
- Synthesis and nuclear magnetic resonance studies of some L-fucosyl-containing disaccharidesJournal of the Chemical Society, Perkin Transactions 1, 1991
- Carbon-13 magnetic resonance. VII. Steric perturbation of the carbon-13 chemical shiftJournal of the American Chemical Society, 1967