Isolation and structural determination of octacyanobutanediide, [C4(CN)8]2−; precursors to M(TCNE)x magnets‡

Abstract
The reaction of MI2·xMe3CN (M = Mn, Fe) and TCNE (tetracyanoethylene) leads to unprecedented [C4(CN)8]2– µ4-metal complexes which have been crystallographically characterized and are precursors to M(TCNE)x·yS magnets.

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