Thermal decomposition of 1,1,2,2-tetrafluorocyclobutane at low pressures
- 1 January 1981
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases
- Vol. 77 (3) , 709-710
- https://doi.org/10.1039/f19817700709
Abstract
The relative rates of the two unimolecular decomposition channels have been determined as a function of pressure at 542.2 °C. These have been compared with RRKM calculations based on a step-ladder model for collisional energy transfer. The results are consistent with an average value of ΔE≈ 12 kJ mol–1.Keywords
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