Reactivity of cis-Bis(dimethylphenylsilyl)bis(phosphine)platinum Complexes toward Unsaturated Compounds Relevant to Double Silylation
- 1 March 1989
- journal article
- research article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 18 (3) , 467-470
- https://doi.org/10.1246/cl.1989.467
Abstract
The reaction of phenylacetylene, tolane, or isoprene with cis-bis(dimethylphenylsilyl)bis(methyldiphenylphosphine)platinum readily took place to result in 1,2- or 1,4- double silylation, respectively. Ethylene also underwent double silylation with the platinum complex, but styrene selectively gave E-2-(dimethylphenylsilyl)styrene.Keywords
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