Ziegler–Natta catalysis: an alternative mechanism involving metallacycles
- 1 January 1980
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 11,p. 490-492
- https://doi.org/10.1039/c39800000490
Abstract
Semi-empirical molecular orbital calculations suggest a new catalytic sequence for Ziegler–Natta polymerization involving a metallacyclopentane intermediate.Keywords
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