Rhodium–platinum cluster compounds. Relationships with olefin–platinum complexes and X-ray crystal structures of [PtRh4(µ-CO)4(η-C5Me5)4] and [PtRh2(µ-H)(µ-CO)2(CO)(PPh3)(η-C5Me5)2][BF4]
- 1 January 1981
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 16,p. 869-871
- https://doi.org/10.1039/c39810000869
Abstract
The cluster compounds [PtRh4(µ-CO)4(η-C5Me5)4] and [PtRh2(µ-H)(µ-CO)2(CO)(PPh3)(η-C5Me5)2][BF4] have been prepared and their structures established by X ray diffraction; the dirhodium–platinum species undergoes novel dynamic behaviour in solution, revealed by n.m.r. studies, as do other salts of this type.Keywords
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