Quantitative measurement of syn stabilization of lithiated aldimines
- 1 January 1979
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 1,p. 47-48
- https://doi.org/10.1039/c39790000047
Abstract
The lithiation and alkylation of aliphatic aldimines has been shown to give syn and anti products in a ratio of 96:4 which is interpreted as representing a minimum value for the syn to anti ratio of the lithiated aldimine intermediates; the factor responsible for the preferential syn stabilization, though not yet identified, is determined to have a magnitude of at least 18 kJ mol–1.Keywords
This publication has 0 references indexed in Scilit: