Phosphaazaallene and phosphinylimide complexes stemming from a terminal and four-coordinate titanium phosphinidene
- 14 October 2003
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Dalton Transactions
- No. 22,p. 4228-4229
- https://doi.org/10.1039/b311748k
Abstract
Treatment of the terminal titanium–phosphinidene (Nacnac)TiPMes*(CH2 tBu) (Nacnac− = [2,6-iPr2C6H3]–NC(CH3)CHC(CH3)N[2,6-iPr2C6H3], Mes*− = 2,4,6-tBu3C6H2) with CNtBu and N2CPh2, in pentane at −35 °C, affords η2-(N,C)-phosphaazaallene and phosphinylimide complexes, respectively.Keywords
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