ABSOLUTE CONFIGURATION OF POLYPEPTIDE AND DYE COMPLEXES BY AN APPLICATION OF THE EXCITON CHIRALITY METHOD
- 5 January 1983
- journal article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 12 (1) , 47-50
- https://doi.org/10.1246/cl.1983.47
Abstract
Absolute configurations of the poly(Nε-alkyl-l-lysine) and alkylamino azo dye complexes have been examined by the exciton chirality method. Most complexes showed the S-chirality of the dipole transition moments of dyes. Increased hydrophobic property changed the chirality of dye from common S- to uncommon R-chirality.This publication has 3 references indexed in Scilit:
- Circular dichroism of N‐phenylnaphthylamine derivatives complexed with the β‐form of poly(L‐lysine)Biopolymers, 1980
- Induced optical activity in poly‐L‐lysine–methyl orange systemBiopolymers, 1973
- Exciton chirality method and its application to configurational and conformational studies of natural productsAccounts of Chemical Research, 1972